Stereoselective Synthesis of the Pheromones of Ant Tetramorium Impurm and Leptogenys Diminuta |
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Authors: | LI Yan HUANG Jin xia ZHOU Zhong qiang CHEN Zu xing and XU Zhang huang |
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Institution: | LI Yan **,HUANG Jin xia,ZHOU Zhong qiang,CHEN Zu xing and XU Zhang huang |
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Abstract: | R,4S ) 4 Methyl 3 hexanol and ( 3R,4S ) 4 methyl 3 heptanol, which are the pheromones of ant Tetramorium impurm and Leptogenys diminuta , were stereoselectively synthesized by six step sequence starting from N bornane 10,2 sultam separately, the two asymmetric carbon atoms of the target products were created by employing asymmetric syn aldolization of N acylbornane 10,2 sultam with propylaldehyde. The enantiomeric excess of the target products prepared by this route is over 92%. |
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Keywords: | Pheromone Asymmetric syn aldolization N Bornane 10 2 sultam |
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