Epimination of olefins by means of 3,3-pentamethyleneoxaziridine — A one-step synthesis of aziridines |
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Authors: | E Schmitz K Janisch |
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Institution: | 1. Central Institute of Organic Chemistry, Academy of Sciences of the German Democratic Republic, Berlin-Adlershof
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Abstract: | 3,3-Pentamethyleneoxaziridine, which is readily obtained by treatment of cyclohexanone with ammonia and sodium hypochlorite or hydroxylamine-O-sulfonic acid, reacts with olefins with transfer of the NH group to give aziridines. Aziridines were obtained from styrene, ring- or side-chain-substituted styrenes, norbornene, and acrylonitrile in 20–70% yields. Cyclohexene is doubly aminated to give N-aminoaziridine. Nitriles are formed from phenylacetylene and diphenylacetylene as a result of rearrangement. |
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