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Facile synthesis and characterization of novel thermo-chromism cholesteryl-containing hydrogen-bonded liquid crystals
Authors:Wan Li He  Tao Liu  Zhou Yang  Dong Yu Zhao  Wei Huang  Hui Cao  Guo Jie Wang  Huai Yang
Affiliation:Department of Materials Physics and Chemistry, School of Materials Science and Engineering, University of Science and Technology Beijing, Beijing 100083, China
Abstract:Two series of novel cholesteryl-containing H-bonded liquid crystals were prepared through facile self-assembly between cholesteryl isonicotinate(proton acceptor) exhibiting a monotropic cholesteric phase,and the 4-alkoxy-benzoic acid or 4-alkoxy cinnamic acid(proton donor).It was found that the increase of the conjugate length as well as the terminal length can contribute to enhance the interaction of molecules and thus significantly influenced the thermal behaviors of H-bonded LCs.The cholesteric reflectio...
Keywords:Liquid crystal  Hydrogen bond  Serf-assembly  Selective reflection  Thermo-chromism
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