Facile synthesis and characterization of novel thermo-chromism cholesteryl-containing hydrogen-bonded liquid crystals |
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Authors: | Wan Li He Tao Liu Zhou Yang Dong Yu Zhao Wei Huang Hui Cao Guo Jie Wang Huai Yang |
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Affiliation: | Department of Materials Physics and Chemistry, School of Materials Science and Engineering, University of Science and Technology Beijing, Beijing 100083, China |
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Abstract: | Two series of novel cholesteryl-containing H-bonded liquid crystals were prepared through facile self-assembly between cholesteryl isonicotinate(proton acceptor) exhibiting a monotropic cholesteric phase,and the 4-alkoxy-benzoic acid or 4-alkoxy cinnamic acid(proton donor).It was found that the increase of the conjugate length as well as the terminal length can contribute to enhance the interaction of molecules and thus significantly influenced the thermal behaviors of H-bonded LCs.The cholesteric reflectio... |
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Keywords: | Liquid crystal Hydrogen bond Serf-assembly Selective reflection Thermo-chromism |
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