| Recent Advances in Organic Reactions Catalyzed by Lanthanide(III) Complexes |
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| 作者姓名： | 陈瑞芳 钱长涛 |
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| 作者单位： | CHEN，Rui Fang QIAN，Chang Tao State Key Laboratory of Organometallic Chemistry，Shanghai Institute of Organic Chemistry，Chinese Academy of Sciences，Shanghai 200032，China |
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| 基金项目： | ProjectsupportedbytheNationalNaturalScienceFoundationofChinaandtheMajorStateBasicResearchDevelopmentProgram(No.G2 0 0 0 0 4 80 0 7) |
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| 摘 要： | Ｉｎｔｒｏｄｕｃｔｉｏｎ Ｔｈｅｎａｍｅ“ｒａｒｅｅａｒｔｈ”ａｐｐｌｉｅｓｔｏｔｈｅｌａｎｔｈａｎｉｄｅｓ ,ｙｔｔｒｉｕｍａｎｄｓｃａｎｄｉｕｍ .Ｔｈｅ 15ｅｌｅｍｅｎｔｓｏｆｌａｎｔｈａｎｉｄｅｆｒｏｍｌａｎｔｈａｎｕｍｔｏｌｕｔｅｔｉｕｍｃｏｎｓｔｉｔｕｔｅａｕｎｉｑｕｅｆａｍｉｌｙｏｆｃｌｏｓｅｌｙｒｅｌａｔｅｄｅｌｅｍｅｎｔｓ (ｔｈｅｄｉｆｆｅｒｅｎｃｅｌｙｉｎｇｉｎｔｈｅｎｕｍ ｂｅｒｏｆ 4ｆｅｌｅｔｒｏｎｓ)ｆｒｏｍｗｈｉｃｈｒｅｇｅｎｔｓｏｒｃａｔａｌｙｓｔｓｗｉｔｈ“ｔｕｎａｂ…
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Recent Advances in Organic Reactions Catalyzed by Lanthanide(III) Complexes |
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| Abstract: | Lanthanide compounds have been attracting much attention in organic synthesis. Chiral Ln substituted BINOL have been widely studied in several asymmetric organic reactions. LnCl 3 and Ln(OTf) 3 have been expected to serve as Lewis acids and have been applied to many important synthetic reactions in a one pot manner. Ln(O i Pr) 3 exhibits some basic characters, which also can be utilized in some special organic transformation. This article deals with some lanthanides(III) complexes promoted organic reactions, which we have recently developed. |
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| Keywords: | lanthanide chiral Ln BINOL LnCl 3 Ln(OTf) 3 organic reaction |
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