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Tandem radical rearrangement/Pd-catalysed translocation of bicyclo[2.2.2]lactones. An efficient access to the oxa-triquinane core structure
Authors:Liao Jyh-Hsiung  Maulide Nuno  Augustyns Benoît  Markó István E
Institution:Université catholique de Louvain, Département de Chimie, Batiment Lavoisier, Place Louis Pasteur 1, 1348, Louvain-la-Neuve, Belgium.
Abstract:The skeletal rearrangement of bicyclo2.2.2]lactones, involving a mild and chemoselective palladium-catalysed translocation key-step, provides an efficient and diastereoselective access to synthetically useful bicyclo3.3.0]lactones.
Keywords:
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