Tandem radical rearrangement/Pd-catalysed translocation of bicyclo[2.2.2]lactones. An efficient access to the oxa-triquinane core structure |
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Authors: | Liao Jyh-Hsiung Maulide Nuno Augustyns Benoît Markó István E |
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Institution: | Université catholique de Louvain, Département de Chimie, Batiment Lavoisier, Place Louis Pasteur 1, 1348, Louvain-la-Neuve, Belgium. |
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Abstract: | The skeletal rearrangement of bicyclo2.2.2]lactones, involving a mild and chemoselective palladium-catalysed translocation key-step, provides an efficient and diastereoselective access to synthetically useful bicyclo3.3.0]lactones. |
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