| 二维层状聚合物{[Zn(C4H4O6)(H2O)]2·3H2O)}n的合成与表征 |
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| 引用本文： | 林宏艳,胡海良,陈宝宽,李锦. 二维层状聚合物{[Zn(C4H4O6)(H2O)]2·3H2O)}n的合成与表征[J]. 光谱实验室, 2009, 26(4): 803-806 |
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| 作者姓名： | 林宏艳 胡海良 陈宝宽 李锦 |
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| 作者单位： | 渤海大学化学化工学院,辽宁省锦州市高新技术产业区科技路19号,121000;渤海大学化学化工学院,辽宁省锦州市高新技术产业区科技路19号,121000;渤海大学化学化工学院,辽宁省锦州市高新技术产业区科技路19号,121000;渤海大学化学化工学院,辽宁省锦州市高新技术产业区科技路19号,121000 |
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| 基金项目： | 辽宁省自然科学基金，辽宁省教育厅科研基金 |
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| 摘 要： | 室温条件下合成了一种新的基于酒石酸的Zn^2＋配位聚合物{[Zn（C4H4O6）（H2O）]2.3H2O}n,通过X射线单晶衍射法、元素分析以及红外光谱对其结构进行了表征。结果表明,该聚合物中Zn^2＋是六配位的扭曲八面体几何构型,酒石酸采取两种不同的配位模式交替连接Zn^2＋离子形成二维层状结构,并对聚合物的荧光性质进行了研究。
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| 关 键 词： | 酒石酸 Zn2+配位聚合物 晶体结构 光谱表征 |
Synthesis and Characterization of a New Two-Dimensional Compound:{[Zn(C4H4O6)(H2O)]23H2O}n |
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| Lin Hong-Yan,Hu Hai-Liang,Chen Bao-Kuan,LI Jin. Synthesis and Characterization of a New Two-Dimensional Compound:{[Zn(C4H4O6)(H2O)]23H2O}n[J]. Chinese Journal of Spectroscopy Laboratory, 2009, 26(4): 803-806 |
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| Authors: | Lin Hong-Yan Hu Hai-Liang Chen Bao-Kuan LI Jin |
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| Affiliation: | LIN Hong-Yan Hu Hai-Liang CHEN Bao-Kuan LI Jin (Faculty of Chemistry and Chemical Engineering ,Bohai University ,J inzhou , Liaoning 121000,P. R. China) |
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| Abstract: | A new Zn^2＋ coordination polymer based on tartaric acid,{[Zn（C4H4O6）（H2O）]2·3H2O}n,was synthesized under open-air mild reaction conditions,and structurally characterized by IR,element analysis and single-crystal X-ray diffraction. X-ray diffraction analysis reveals that Zn ions keeps its six-coordinate in a distorted octahedron geometry. The adjacent Zn ions were linked by bridging tartaric acid to form a two-dimensional layer,in which tartaric acid adopted two different coordinated modes.The fluorescence property of the title compound was also studied. |
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| Keywords: | Tartaric Acid Zn^2＋ Compound Crystal Structure Spectral Characterization |
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