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Calculation of the spectroscopic parameters of van der waals diatomic molecules: An excited alkali Na or K atom and an inert gas atom
Authors:A V Glushkov  S V Orlov
Abstract:The interatomic potentials in a system of an excited Na or K atom and an inert gas atom are calculated on the basis of the effective pseudopotential method, using a new form of the polarization interaction potential obtained by calculating the most important polarization diagrams of perturbation theory in the Thomas-Fermi approximation. The results of a calculation, on its basis, of the intermolecular terms of this van der Waals system are given, refining the existing data; some of the results have been obtained for the first time. A comparison is made with the available experimental and theoretical data. Odessa Hydrometeorological Institute. Translated from Izvestiya Vysshikh Uchebnykh Zavedenii, Fizika, No. 9, pp. 32–35, September, 1996.
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