Dithiocarboxylierung von α-Stickstoff-Carbanionen |
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Authors: | Petra Kindt Wolfgang Dölling Manfred Augustin |
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Affiliation: | (1) Sektion Chemie, Martin-Luther-Universität Halle-Wittenberg, DDR-4050 Halle (Saale), Deutsche Demokratische Republik |
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Abstract: | Summary Dithiocarbamic acid esters1 with CH-acidic methylene group adjacent to nitrogen react in the system dimethylformamide +2 equivalent sodiumtert. butoxide with carbon disulphide yielding 1,3-thiazoline-2-thiones3. 2,5-Bis(alkylthio)-1,3,-thiazoles6 are available via dithiocarboxylation of isothiocyanate5. |
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Keywords: | Dithiocarbamic acid esters 1,3-Thiazoline-2-thiones 2-Alkylthio-1,3-thiazoles 1,3-Thiazole-derivatives |
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