Helium diffusion in aqueous sodium chloride solution at high pressures |
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Authors: | D?V?Ivlev Email author" target="_blank">M?G?KiselevEmail author |
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Institution: | 1.Krestov Institute of Solution Chemistry,Russian Academy of Sciences,Ivanovo,Russia |
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Abstract: | A molecular dynamic investigation of self-diffusion coefficients of helium and water in aqueous NaCl solution is performed.
To understand the nonlinear behavior of the self-diffusion coefficients, a number of structural characteristics (radial distribution
functions, hydrogen bond network topology) are calculated. The electrolyte concentration range is discussed in which a local
increase in helium self-diffusion coefficient is observed. It is shown that this behavior is caused by a breakdown of the
network of hydrogen bonds due to competition between ion positions in the states of solvent-separated and contact pairs. |
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