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Selective synthesis of clamshell-type bis-phthalocyanine bearing tetrachlorocyclotriphosphazene intramolecular bridge
Affiliation:1. Institute of Physiologically Active Compounds, Federal Research Center of Problems of Chemical Physics and Medicinal Chemistry, Russian Academy of Sciences, 142432 Chernogolovka, Moscow Region, Russian Federation;2. A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 119991 Moscow, Russian Federation
Abstract:The selective synthesis of clamshell-type bis-phthalocyanine was performed using cyclotriphosphazene as a peripheral spacer. The spectral characteristics of the target dye are similar to those of most H-dimers, and the reaction can be considered conditionally selective with respect to the cis-isomer
Keywords:phthalocyanines  phosphazenes  H-dimers  clamshell dimers  dyes  UV-VIS  NMR
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