Synthesis, Characterization and Crystal Structure of a New Cobalt Phosphomolybdate that Contains [(Mo16O32)Co16(H2O)18(PO4)6(HPO4)18] Wheels |
| |
| Authors: | Ying Ma Yangguang Li Enbo Wang Ying Lu Xinxin Xu Xiuli Bai |
| |
| Institution: | (1) Institute of Polyoxometalate Chemistry, Department of Chemistry, Northeast Normal University, Changchun, 130024, P.R. China |
| |
| Abstract: | A new compound, Co(H2O)6]{Co2(H2O)6}{Co(H2PO4)2}{(PO4)6(HPO4)18(Mo16O32)Co16(H2O)18}] · 23H2O (1), has been prepared under mild hydrothermal conditions and structurally characterized by elemental analyses, i.r. spectrum,
XPS spectrum and single-crystal X-ray diffraction. Compound (1) consists of (Mo16O32)Co16- (H2O)18(PO4)6(HPO4)18] wheel-shape clusters as the structural motif, which are covalently linked by Co2(H2O)6] and Co(H2PO4)2] fragments to form a two-dimensional layer framework. It is the first time that such wheels have been linked by both mononuclear
and dimeric CoII octahedra.
Electronic supplementary material Electronic supplementary material is available for this article at
and accessible for authorised users. |
| |
| Keywords: | |
| 本文献已被 SpringerLink 等数据库收录！ |
|
