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Room-temperature epitaxial growth of CeO2(001) films on YSZ buffered Si(001) substrates
Authors:V Trtík  F Sánchez  R Aguiar  Y Maniette  C Ferrater  M Varela
Institution:(1) Universitat de Barcelona, Departament de Física Aplicada i Electrònica, Avda. Diagonal 647, E-08028 Barcelona, Spain (Fax: +34-34021138, E-mail: mvarela@fae.ub.es), ES;(2) Universitat de Barcelona, Serveis Cientifico-Tècnics, C. Marti i Franques s/n, E-08028 Barcelona, Spain, ES
Abstract:2 (001) epitaxial thin films deposited on Si(001) with yttria-stabilized zirconia buffers have been obtained for the first time at room temperature by pulsed-laser deposition. The influence of oxygen pressure on the crystal quality of CeO2 was studied for the films deposited at 100 °C. The rocking curve full width at half maximum of the CeO2(002) peak for films deposited at room temperature and 100 °C was between 1° and 2°, for oxygen pressures below 3×10-2 mbar. The best crystal quality was obtained at around 3×10-3 mbar. Epitaxial growth at room temperature was confirmed by cross-sectional transmission electron microscopy. Scanning electron microscopy and atomic force microscopy revealed very smooth surfaces for oxygen pressure below 3×10-2 mbar, with rms roughness values around 0.3 nm over 5 μm×5 μm. Received: 25 September 1997/Accepted: 22 April 1998
Keywords:PACS: 68  55  81  15 Z
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