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Room-Temperature Bismuth-Catalyzed Bis-arylation of Carbonyl Compounds with Aryl Ethers and Phenols
Authors:Congrong Liu  Manbo Li
Institution:[1]School of Environment Engineering, Nanjing Institute of Technology, Nanjing, Jiangsu 211167, China [2]Joint Laboratory of Green Synthetic Chemistry, Department of Chemistry, University of Science and Technology of China, Hefei, Anhui 230026, China
Abstract:Using Bi2(SO4)3 as the catalyst and TMSCl as the additive, a wide variety of aldehydes, ketones, and acetals were smoothly condensed with aryl ethers at room temperature to provide the corresponding diarylmethanes and triarylmethanes selectively in good to excellent yields.
Keywords:carbonyl compounds  aryl ethers  condensation  bismuth  chlorotrimethylsilane
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