Alternative paths in the ring opening of oxadiaziridine: The diimide N-oxide versus the oxodiimide rearrangement |
| |
| Authors: | Renzo Cimiraglia Maurizio Persico Jacopo Tomasi |
| |
| Affiliation: | (1) Istituto di Chimica Fisica dell'Università di Pisa, Via Risorgimento, 35, I-56100 Pisa, Italy;(2) Laboratorio di Chimica Quantistica ed Energetica Molecolare del C.N.R., Via Risorgimento, 35, I-56100 Pisa, Italy |
| |
| Abstract: | The ring opening of the oxadiaziridine by cleavage of the N-N bond has been theoretically investigated by SCF calculations improved with limited CI. The possible competition of this reaction with the better known ones (N-O bond cleavage, inversion of the N atom) is discussed. The chemical implications of the formation of a new type of 1,3-dipole are examined. |
| |
| Keywords: | Ring opening reactions 1,3-Dipoles Diimide N-oxide interconversion mechanisms |
| 本文献已被 SpringerLink 等数据库收录！ |
|
