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Unexpected effects of trace impurities on the properties of polymer-stabilized ruthenium colloids from different sources of ruthenium(III) chloride hydrate
Authors:Liu Manhong  He Baolin  Liu Hanfan  Yan Xiaoping
Affiliation:PCLCC (Polymer Chemistry Laboratory, Chinese Academy of Sciences and China Petro-Chemical Corporation), Center for Molecular Science, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100080, China.
Abstract:The stability and the catalytic performances of polyvinylpyrrolidone-stabilized ruthenium colloids (PVP-Ru) prepared by using RuCl(3).xH(2)O of different sources have been investigated. The trace impurity content of platinum and palladium in RuCl(3).xH(2)O was demonstrated to be the main factors affecting the properties of PVP-Ru colloids.
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