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Synthesis of ortho- and para-quinones of the benzindole series
Authors:I. N. Nesterova  A. N. Grinev  N. M. Rubtsov
Affiliation:(1) S. Ordzhonikidze All-Union Scientific Research Chemical Pharmaceutical Institute, 119021 Moscow
Abstract:Ethyl esters of agr-(3-chloro-1,4-naphthoquinon-3-yl)crotonic or cinnamic acids were obtained by the reaction of 2,3-dichloro-1,4-naphthoquinone with ethyl esters of N-substituted Bgr-aminocrotonic or Bgr-aminocinnamic acids. These esters were converted by alkaline fusion into benz[f]indole-4,9-dione-3-carboxylic acids, and into ethyl esters of benz[g]indole-4,5-dione-3-carboxylic acid by the action of acetic acid.Deceased.Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 1, pp. 66–68, January, 1989.
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