| (Salen)Ti(IV)-Catalyzed Asymmetric Ring-opening of meso Epoxides Using Dithiophosphorus Acid as the Nucleophile |
| |
| 引用本文： | Zheng Hong ZHOU,Zhao Ming LI,Bing LIU,Kang Ying LI,Li Xin WANG,Guo Feng ZHAO,Qi Lin ZHOU,Chu Chi TANG State Key Laboratory of Elemento-Organic Chemistry,Institute of Elemento-Organic Chemistry,Nankai University,Tianjin 300071. (Salen)Ti(IV)-Catalyzed Asymmetric Ring-opening of meso Epoxides Using Dithiophosphorus Acid as the Nucleophile[J]. 中国化学快报, 2006, 0(2) |
| |
| 作者姓名： | Zheng Hong ZHOU Zhao Ming LI Bing LIU Kang Ying LI Li Xin WANG Guo Feng ZHAO Qi Lin ZHOU Chu Chi TANG State Key Laboratory of Elemento-Organic Chemistry Institute of Elemento-Organic Chemistry Nankai University Tianjin 300071 |
| |
| 作者单位： | Zheng Hong ZHOU，Zhao Ming LI，Bing LIU，Kang Ying LI，Li Xin WANG，Guo Feng ZHAO，Qi Lin ZHOU，Chu Chi TANG State Key Laboratory of Elemento-Organic Chemistry，Institute of Elemento-Organic Chemistry，Nankai University，Tianjin 300071 |
| |
| 摘 要： | As an important strategy for the formation of 1,2-bifunctionalized systems theasymmetric ring-opening of epoxides with different nucleophiles has drawn muchattention from the organic chemists. A wide variety of nucleophiles are utilized in theaforemention…
|
(Salen)Ti(IV)-Catalyzed Asymmetric Ring-opening of meso Epoxides Using Dithiophosphorus Acid as the Nucleophile |
| |
| Zheng Hong ZHOU,Zhao Ming LI,Bing LIU,Kang Ying LI,Li Xin WANG,Guo Feng ZHAO,Qi Lin ZHOU,Chu Chi TANG State Key Laboratory of Elemento-Organic Chemistry. (Salen)Ti(IV)-Catalyzed Asymmetric Ring-opening of meso Epoxides Using Dithiophosphorus Acid as the Nucleophile[J]. Chinese Chemical Letters, 2006, 0(2) |
| |
| Authors: | Zheng Hong ZHOU Zhao Ming LI Bing LIU Kang Ying LI Li Xin WANG Guo Feng ZHAO Qi Lin ZHOU Chu Chi TANG State Key Laboratory of Elemento-Organic Chemistry |
| |
| Affiliation: | Zheng Hong ZHOU,Zhao Ming LI,Bing LIU,Kang Ying LI,Li Xin WANG,Guo Feng ZHAO,Qi Lin ZHOU,Chu Chi TANG State Key Laboratory of Elemento-Organic Chemistry,Institute of Elemento-Organic Chemistry,Nankai University,Tianjin 300071 |
| |
| Abstract: | The asymmetric ring-opening of epoxides with dithiophosphorus acids catalyzed by a(salen)Ti(IV) complex formed in situ from the reaction of Ti(OPr-i)4 and the chiral Schiff basederived from (1R,2R)-( )-diaminocyclohexane was realized. The resulting products wereobtained with low to good enantioselectivity (up to 73% ee). |
| |
| Keywords: | (Salen)Ti(IV) complex ring-opening dithiophosphorus acid enantioselectivity mesoepoxide. |
| 本文献已被 CNKI 等数据库收录！ |
