| 一种新型稀土光转换剂的合成及其与塑料相容性研究 |
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| 引用本文： | 肖尊宏,谭松庭,王霞瑜,邹应萍. 一种新型稀土光转换剂的合成及其与塑料相容性研究[J]. 光谱学与光谱分析, 2005, 25(1): 145-148 |
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| 作者姓名： | 肖尊宏 谭松庭 王霞瑜 邹应萍 |
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| 作者单位： | 1. 许昌卷烟总厂技术中心，河南 许昌 461000
2. 湘潭大学高分子材料研究所，湖南 湘潭 411105 |
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| 基金项目： | 教育部重点项目(01083)，湖南省教育厅重点项目(01A002)资助 |
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| 摘 要： | 用相转移催法合成了长链2-辛基-1, 3-二苯基-1, 3-丙二酮(ODBM)及其Sm的配合物并用IR，EA，UV和1H NMR对化合物进行了表征;Sm配合物粉末及其在PVC，PE中都能在波长650 nm处光致发光;长链的引入使Sm配合物与PVC，PE具有较好的相容性;因此，长链Sm配合物是一种在树脂中相容性好、发光波长与植物光合作用所需的光波长643和660 nm相吻合的光转换剂。
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| 关 键 词： | 光转换剂 Sm的配合物 相容性 光波吻合 |
| 文章编号： | 1000-0593(2005)01-0145-04 |
| 收稿时间： | 2003-03-26 |
| 修稿时间： | 2003-03-26 |
Synthesis of a Novel Rare Earth Light Conversion Agent and Study on Its Compatibility in Plastics |
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| XIAO Zun-hong,TAN Song-ting,WANG Xia-yu,ZOU Ying-ping. Synthesis of a Novel Rare Earth Light Conversion Agent and Study on Its Compatibility in Plastics[J]. Spectroscopy and Spectral Analysis, 2005, 25(1): 145-148 |
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| Authors: | XIAO Zun-hong TAN Song-ting WANG Xia-yu ZOU Ying-ping |
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| Affiliation: | 1. The Technology Center of Xuchang Cigarettes General Factory, Xuchang 461000, China2. Institute of Polymer Material Science, Xiangtan University, Xiangtan 411105, China |
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| Abstract: | octyl-1, 3-diphenol-1, 3-propdione was synthesized by phase transfer catalysis and its Sm complexes were prepared. These compounds were characterized by IR, EA, UV and ~ 1H NMR; Sm complex and its mixture doped with PE and PVC show photoluminescence at 650 nm. There is excellent compatibility between Sm complex and plastics by the addition of long carbon chain. Therefore, Sm complex with long carbon chain is a superior light conversion agent with good compatibility in resins with emission wavelength suitable to the 643 and 660 nm for plants' photosynthesis. |
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| Keywords: | Light conversion agent Sm complex Compatibility Wavelength adaptability |
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