Kinetics and mechanism of oxidation of cyclopentanone by N-bromosuccinimide |
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| Authors: | S. P. Mushran A. K. Bose J. N. Tiwari |
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| Affiliation: | (1) Chemical Laboratories, University of Allahabad, IND-211002 Allahabad, India |
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| Abstract: | N-bromosuccinimide oxidation of cyclopentanone in acidic media in presence of mercuric acetate has been made. A zero order dependance to N-bromosuccinimide and a first order dependence to cyclopentanone and hydrogen ion concentration has been observed. Ionic strength, mercuric acetate and succinimide has negligible effect while methanol addition has a positive effect. Various rate parameters have been computed and 1,2-cyclopentanedione identified as the end product. A suitable mechanism in confirmity with the above observations has been proposed.With 2 Figures |
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