| 配合物[Cd(NIT4Py)2][Au(CN)2]2的合成与晶体结构 |
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| 引用本文： | 王淑萍,张旭红,杨述韬.配合物[Cd(NIT4Py)2][Au(CN)2]2的合成与晶体结构[J].无机化学学报,2007,23(6):1075-1077. |
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| 作者姓名： | 王淑萍 张旭红 杨述韬 |
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| 作者单位： | 河北师范大学化学与材料科学学院,石家庄,050016 |
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| 基金项目： | 河北省教育厅自然科学基金;河北师范大学校科研和教改项目 |
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| 摘 要： | A Cd(II)-nitronyl nitroxide radical complex with dicyanoaurate(I) bridges Cd(NIT4Py)2]Au(CN)2]2, was synthesized and characterized by elemental analyses, IR spectrum and X-ray diffraction single-crystal structure analysis. Crystal data for the complex: triclinic, space group P1, a=0.720 9(11) nm, b=0.960 3(15) nm, c=1.284(2) nm, α=75.38(2)°, β=85.46(2)°, γ=68.38(2)°, V=0.800(2) nm3, Z=1, and R1 I>2σ(I)]=0.055 8. The title complex consists of infinite one-dimensional chains of Cd(NIT4Py)2]Au(CN)2]2, in which Cd(NIT4Py)2] moieties are conne-cted by Au(CN)2]- μ2-bridging ligands. Each cadmium(II) ion is six-coordinated in a distorted and centrosymmetric octahedral environment. CCDC: 258357.
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| 关 键 词： | 氮氧自由基 镉配合物 二氰合金 晶体结构 一维 |
| 文章编号： | 1001-4861（2007）06-1075-03 |
| 修稿时间： | 2006-12-282007-04-28 |
Synthesis and Crystal Structure of Complex [Cd(NIT4Py)2][Au(CN)2]2 |
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| WANG Shu-Ping,ZHANG Xu-Hong and YANG Shu-Tao.Synthesis and Crystal Structure of Complex [Cd(NIT4Py)2][Au(CN)2]2[J].Chinese Journal of Inorganic Chemistry,2007,23(6):1075-1077. |
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| Authors: | WANG Shu-Ping ZHANG Xu-Hong and YANG Shu-Tao |
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| Institution: | College of Chemistry & Material Science, Hebei Normal University, Shijiazhuang 050016,College of Chemistry & Material Science, Hebei Normal University, Shijiazhuang 050016 and College of Chemistry & Material Science, Hebei Normal University, Shijiazhuang 050016 |
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| Abstract: | A Cd(Ⅱ)-nitronyl nitroxide radical complex with dicyanoaurate(Ⅰ) bridges Cd(NIT4Py)2]Au(CN)2]2, was synthesized and characterized by elemental analyses, IR spectrum and X-ray diffraction single-crystal structureanalysis. Crystal data for the complex: triclinic, space group P(-1), a=0.720 9(11) nm, b=0.960 3(15) nm, c=1.284(2)nm, α=75.38(2)°, β=85.46(2)°, γ=68.38(2)°, V=0.800(2) nm3, Z=1, and R1 I＞Iσ(/)]=0.055 8. The title complex consists of infinite one-dimensional chains of Cd(NIT4Py)2]Au(CN)2]2, in which Cd(NIT4Py)2] moieties are conne cted by Au(CN)2]-μ2-bridging ligands. Each cadmium(Ⅱ) ion is six-coordinated in a distorted and centrosymmetric octahedral environment. CCDC: 258357. |
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| Keywords: | nitronyl nitroxide radical cadmium(II) complex dicyanoaurate(I) crystal structure one-dimensional |
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