Thermal analysis and mass spectra of sulfur-containing iron carbonyl complexes |
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| Authors: | M A Dzyubina G N Kuz'mina B I Kolobkov A I Nekhaev |
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| Institution: | 1. A. V. Topchiev Institute of Petrochemical Synthesis, Academy of Sciences of the USSR, Moscow
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| Abstract: | | 1. |
The activation energy for the thermal decomposition of complexes with Fe2(CO)6S2 frameworks amounts to 103–144 kJ/mole.
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Decarbonylation and splitting off of the hydrocarbon part of the molecule is the general pattern of behavior of iron carbonyl compounds with sulfur ligands on heating and under electron bombardment.
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In complexes containing a norbornadiene fragment, a reverse Diels-Alder reaction takes place under electron bombardment, in addition to splitting off of norbornadiene.
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 10, pp. 2286–2292, October, 1988. |
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