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Tri-, penta-, and hexa-phospha ruthenocenes |
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| Authors: | Peter B Hitchcock John F Nixon and Robson M Matos |
| Institution: | a School of Chemistry and Molecular Sciences, University of Sussex, Brighton BN1 9QJ, UK b Departamento de Química, Universidade Federal de Minas Geralis, Avenida Antônio Carlos 6627, Pampulha, Belo Horizonte Minas Gerais, 31270, Brasil |
| Abstract: | Synthesis and structural studies of the ruthenium(II) ‘sandwich’ complexes Ru(η5-P3C2tBu2)2], Ru(η5-P3C2C2tBu2)(η5-P2C3tBu3)], Ru(η5-C5R5)(η5-P3C2tBu2)] (R=H, Me) are described. The results of a single crystal X-ray structural study of Ru(η5-P3C2tBu2)2] are discussed. |
| Keywords: | Ruthenium Ruthenocene Phospharuthenocenes Fluxionality Crystal structure |
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