A general approach to the synthesis of 1-deoxy-L-iminosugars |
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| Authors: | Guaragna Annalisa D'Errico Stefano D'Alonzo Daniele Pedatella Silvana Palumbo Giovanni |
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| Affiliation: | Dipartimento di Chimica Organica e Biochimica, Università di Napoli Federico II, via Cynthia, 4 I-80126 Napoli, Italy. guaragna@unina.it |
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| Abstract: | A stereoselective procedure for the preparation of non-naturally occurring deoxy iminosugars belonging to L-series has been developed. The synthesis involves the construction of the key intermediate bicycle pyperidine 8, available in few steps by the coupling of the heterocyclic synthon 3 and the readily available Garner aldehyde 4. |
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