| 烷基磷(膦)酸萃取剂钠盐及其微乳液的NMR,FTIR光谱研究 |
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| 引用本文： | 傅洵,潘莹,辛惠蓁,胡正水,于卉.烷基磷(膦)酸萃取剂钠盐及其微乳液的NMR,FTIR光谱研究[J].化学学报,1995,53(2):178-182. |
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| 作者姓名： | 傅洵 潘莹 辛惠蓁 胡正水 于卉 |
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| 作者单位： | 青岛化工学院 |
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| 基金项目： | 山东省自然科学基金资助课题 |
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| 摘 要： | 制备了五种皂化度大于97%的无水烷基磷(膦)酸钠盐,用NMR 谱测定了其微乳体系的H化学位移,测定了酸性萃取剂原液,其固体钠盐以及微乳液的FTIR光谱,观察到微乳液中钠盐阴.阳离子都有水化效应,讨论了水合配位与阴离子结构的关系.
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| 关 键 词： | 红外分光光度法 核磁共振谱法 质子磁共振谱法 化学位移 乙基己基膦酸单乙基己酯 付里叶变换 微乳液 山东省自然科学基金 二乙基己基磷酸 烷基磷酸 |
Study on the sodium salts of organo-phosphoric acid extractants and their microemulsions by nmr and ftir spectroscopy |
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| FU XUN,PAN YING,XIN HUIZHEN,HU ZHENGSHUI,YU HUI.Study on the sodium salts of organo-phosphoric acid extractants and their microemulsions by nmr and ftir spectroscopy[J].Acta Chimica Sinica,1995,53(2):178-182. |
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| Authors: | FU XUN PAN YING XIN HUIZHEN HU ZHENGSHUI YU HUI |
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| Abstract: | Five Na salts with > 97% saponified level of alkyl-phosphoric (phosphonic, phosphinic) acid extractants and their microemulsions were prepared and studied by NMR and FTIR spectroscopy. The effects of cation and anion hydration on microemulsion formation and also anion structure effects on hydration are discussed. |
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| Keywords: | INFRARED SPECTROPHOTOMETRY NMR SPECTROMETRY PROTON MAGNETIC RESONANCE SPECTROMETRY CHEMICAL SHIFT ETHYLHEXYL PHOSPHONIC ACID MONOETHYL HEXYLESTER FOURIER TRANSFORM MICROEMULSION ALKYL PHOSPHONIC ACID |
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