| 受阻胺对甲基丙烯酸甲酯聚合的影响 |
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| 引用本文： | 丘坤元,杨英飞,冯新德. 受阻胺对甲基丙烯酸甲酯聚合的影响[J]. 高分子学报, 1987, 0(4): 258-264 |
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| 作者姓名： | 丘坤元 杨英飞 冯新德 |
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| 作者单位： | 北京大学化学系 北京(丘坤元，杨英飞)，北京大学化学系 北京(冯新德) |
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| 摘 要： | 本文研究了受阻胺TMP、TMPM、TUV-770对MMA、St本体聚合的影响。无论用BPO或AlBN引发MMA聚合时,TMPM或TUV-770都能延长诱导期,但对R_p的影响较小,而TMP能使R_p略增。测定了聚合反应的表观活化能和动力学方程。
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| 关 键 词： | 自由基聚合 甲基丙烯酸甲酯 受阻胺 聚合表观活化能 聚合速度方程 |
| 收稿时间： | 1985-02-28 |
THE EFFECTS OF HINDERED AMINES ON METHYL METHACRYLATE POLYMERIZATION |
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| QIU Kun-yuan,YANG Ying-fei,FENG Xin-de. THE EFFECTS OF HINDERED AMINES ON METHYL METHACRYLATE POLYMERIZATION[J]. Acta Polymerica Sinica, 1987, 0(4): 258-264 |
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| Authors: | QIU Kun-yuan YANG Ying-fei FENG Xin-de |
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| Affiliation: | Department of Chemistry; Peking University; Beijing |
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| Abstract: | The effects of hindered amines, such as 2,2,6,6-tetramethyl-4-hydroxy-piperidine (TMP)> 2,2,6,6-tetramethyl-4-piperidinyl methacrylate (TMPM), TUV-770, on methyl methacrylate (MMA) and styrene (St) homopolymerization have been studied. It was found that in the MMA polymerization initiated by benzoyl peroxide (BPO) or 2,2'-azo-bis-isobutylonitrile (AIBN), the presence of TMPM or TUV-770 delayed the induction period and a little change on Rp was observed. However, in the presence of TMP Rp increased slightly. The activation enrgy of polymerization was datermined, and the polymerization rate equation for BPO-TMPM system is obtained as follows: RP = X[BPO]1/2 [MMA] . |
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| Keywords: | Free Radical Polymerization Methyl Methacrylate (MMA) Effects of Hindered Amines Activation Enrgy of Polymerization Rate Equation of Polymerization |
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