Modular face-to-face assembly of multichromophore arrays that absorb across the complete UV-visible spectrum and into the near-IR |
| |
Authors: | Zhao Zhixin Cammidge Andrew N Hughes David L Cook Michael J |
| |
Affiliation: | School of Chemistry, University of East Anglia, Norwich NR4 7TJ, UK. |
| |
Abstract: | Defined face-to-face structures of phthalocyanine and porphyrin chromophores can be prepared using a modular strategy that allows directional, stepwise construction. μ-Oxo linkage between the central group of 14 metalloid atoms Si and Ge ensures π-overlap between the macrocycles, and exciton coupling effects further extend the absorption profile to provide arrays that absorb across the whole UV-visible spectrum and into the near-IR. The strategy is sufficiently versatile to be extended to synthesis of higher defined oligomers and subsequent functionalization or attachment at either or both ends of the stack. |
| |
Keywords: | |
本文献已被 PubMed 等数据库收录! |
|