3]Rotaxane-based dinuclear palladium catalysts for ring-closure Mizoroki-Heck reaction |
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| Authors: | Suzaki Yuji Shimada Kyoichi Chihara Eriko Saito Takashi Tsuchido Yoshitaka Osakada Kohtaro |
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| Institution: | Chemical Resources Laboratory R1-3, Tokyo Institute of Technology, 4259 Nagatsuta, Yokohama 226-8503, Japan. |
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| Abstract: | 3]Rotaxane containing two Pd centers in the cyclic compounds catalyzes a Mizoroki-Heck reaction of substrates with two iodophenyl groups with bisacrylate. Formation of the cyclic products is enhanced by the rotaxane catalyst more smoothly than Pd(OAc)(2). |
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