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Controlling wear failure of graphite-like carbon film in aqueous environment: Two feasible approaches
Authors:Yongxin Wang  Liping Wang  Qunji Xue
Affiliation:a State Key Laboratory of Solid Lubrication, Lanzhou Institute of Chemical Physics, Chinese Academy of Science, Lanzhou 730000, PR China
b Graduate School of the Chinese Academy of Sciences, Beijing 100039, PR China
Abstract:Friction and wear behaviors of graphite-like carbon (GLC) films in aqueous environment were investigated by a reciprocating sliding tribo-meter with ball-on-disc contact. Film structures and wear scars were studied by scanning electron microscope (SEM), energy dispersive spectroscopy (EDS) and a non-contact 3D surface profiler. A comprehensive wear model of the GLC film in aqueous environment was established, and two feasible approaches to control critical factor to the corresponding wear failure were discussed. Results showed that wear loss of GLC films in aqueous environment was characterized by micro-plough and local delamination. Due to the significant material loss, local delamination of films was critical to wear failure of GLC film in aqueous environment if the film was not prepared properly. The initiation and propagation of micro-cracks within whole films closely related to the occurrence of the films delamination from the interface between interlayer and substrate. The increase of film density by adjusting the deposition condition would significantly reduce the film delamination from substrate, meanwhile, fabricating a proper interlayer between substrate and GLC films to prevent the penetration of water molecules into the interface between interlayer and substrate could effectively eliminate the delamination.
Keywords:Graphite-like carbon   Wear model   Delamination   Film density   Interlayer
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