The use of a perylenediimide derivative as a dopant in hole transport layer of an organic light emitting device

A perylene diimide (PDI) derivative was used as a dopant in the hole transport layer (HTL) of an organic light emitting device. The HTL examined was poly (N-vinylcarbazole) (PVK) and the PDI used was N,N′-di-dodecylperylene-3,4,9,10-bis-(dicarboximide), (N-DODEPER). The structure of the device was ITO/PEDOT:PSS (70 nm)/PVK:N-DODEPER(0, 0.2, 0.4, 0.8 wt.%) (65 nm)/Alq₃ (35 nm)/LiF (1.3 nm)/Al (100 nm). 0.8 wt.% N-DODEPER presence exhibited a luminous efficiency of 7.87 cd/A and an external quantum efficiency of 0.78% at 21 mA/cm² and a power efficiency of 3l m/W at 12 mA/cm². The luminous and power efficiency values were significantly enhanced by a factor of 15 with respect to that of undoped device.