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A novel method for preparation of 8-hydroxyquinoline functionalized mesoporous silica: Aluminum complexes and photoluminescence studies |
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| Authors: | Alireza Badiei Hassan GoldoozGhodsi Mohammadi Ziarani |
| Affiliation: | a School of Chemistry, College of Science, University of Tehran, P.O. Box 14155-6455, Tehran, Iran b Department of Chemistry, Tarbiat Modares University, Tehran, Iran c Department of Chemistry, Faculty of Science, Alzahra University, Tehran, Iran |
| Abstract: | 8-Hydroxyquinoline (8-HQ) was attached to mesoporous silica by sulfonamide bond formation between 8-hydroxyquinoline-5-sulfonyl chloride (8-HQ-SO2Cl) and aminopropyl functionalized SBA-15 (designated as SBA-SPS-Q) and then aluminum complexes of 8-HQ was covalently bonded to SBA-SPS-Q using coordinating ability of grafted 8-HQ.The prepared materials were characterized by powder X-ray diffraction (XRD), nitrogen adsorption-desorption, Fourier transform infrared (FT-IR), thermal analysis (TGA-DTA), scanning electron microscopy (SEM), transmission electron microscopy (TEM), elemental analysis and fluorescence spectra. The environmental effects on the emission spectra of grafted 8-HQ and its complexes were studied and discussed in details. |
| Keywords: | Mesoporous silica SBA-15 Tris(8-hydroxyquinoline)aluminum Sulfonamide Emission spectra |
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