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Characterization of DC reactive magnetron sputtered NiO films using spectroscopic ellipsometry
Authors:TC Peng  XH Xiao  XY HanXD Zhou  W Wu  F Ren  CZ Jiang
Institution:a Key Laboratory of Artificial Micro- and Nano-structures of Ministry of Education, Wuhan University, Wuhan 430072, PR China
b State Key Laboratory of Electronic Thin Films and Integrated Devices, University of Electronic Science and Technology of China, Chengdu 610054, PR China
c Center for Electron Microscopy, School of Physics and Technology, Wuhan University, Wuhan 430072, PR China
d School of Physics, Huazhong University of Science and Technology, Wuhan 430074, PR China
Abstract:Thin NiO films were deposited at 500 °C on n-type Si(1 1 1) by a DC reactive magnetron sputtering in a gas mixture of oxygen and argon. The ratio between the flow rates of oxygen and argon was respectively set at 1:4, 1:2, and 1:1. The dependence of structures and optical properties of NiO films were investigated using grazing incidence X-ray diffraction and spectroscopic ellipsometry in the spectral region of 1.5-5.0 eV. Ni-rich NiO films were obtained when the ratio between the flow rates of oxygen and argon was 1:4 and 1:2 in sputtering process. And when the ratio was 1:1, a relatively pure NiO film was formed. The partial pressure of oxygen could significantly influence the thickness and roughness of films. Refractive index n, extinction coefficient k, and direct gap energy and indirect gap energy of the NiO films were also subject to the influence of the partial pressure of oxygen.
Keywords:NiO films  Spectroscopic ellipsometry  Tauc-Lorentz dispersion function
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