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Preparation, characterization, and photocatalytic properties of silver carbonate
Authors:Chengwei Xu  Yuanyuan Liu  Baibiao Huang  Hui LiXiaoyan Qin  Xiaoyang ZhangYing Dai
Institution:a Department of Laboratory Medicine, The Second Hospital of Shandong University, Jinan 250033, PR China
b State Key Lab of Crystal Materials, Shandong University, Jinan 250100, PR China
c Department of Chemistry, Shandong Experimental Senior High School, Jinan,250001, PR China
d School of Physics, Shandong University, Jinan 250100, PR China
Abstract:Silver carbonate (Ag2CO3) short rods were prepared using a precipitation method. It was characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), diffuse reflective spectra (DRS) and photocatalytic degradation of organic pollutants and destruction of E. coli measurements. The results of DRS suggested that the optical transition of Ag2CO3 was indirectly allowed, and its band gap was determined to be 2.08 eV. The prepared Ag2CO3 displayed a high activity towards degradation of phenol and MB under visible light. The total organic carbon (TOC) value decreased during the photocatalytic process, which suggests that phenol was truly photodegraded. The stability of Ag2CO3 was greatly improved when Na2CO3 was added into the photocatalytic system. In addition, Ag2CO3 displayed enhanced photocatalytic activities for the destruction of E. coli due to its photogenerated electron-hole pairs.
Keywords:Silver carbonate  Photocatalysis  Antibacterial activity
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