Effect of laser treatment on the surface of copper alloys

The paper presents the results of laser cleaning of the archaeological metal objects using two time widths of pulsed laser radiation, which are around 150 μs and around 120 ns. Two archaeological objects made of copper alloys were studied: a bow and a ring. Both objects came from a cemetery which is located in the garden complex of Wilanow Palace in Warsaw and are dated from XII to XIII century. The bow and bronze ring had ornamental longitudinal grooving and were part of burial jewellery. The materials of which these artefacts were made of, as well as corrosion products on these objects, were studied by using a variety of analytical techniques. The phase composition of the corrosion layers was determined by using Raman spectroscopy. The surface topography as well as the chemical composition of the deposits and cleaned surfaces were investigated. The samples were examined using scanning electron microscopes equipped with EDS. The investigations included observations in SE and BSE modes and point analyses of the chemical composition by EDS.