Palladium-catalyzed allylic oxidation of olefins by t-butyl hydroperoxide and tellurium(IV) oxide |
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| Authors: | Sakae Uemura Shin-ichi Fukuzawa Akio Toshimitsu Masaya Okano |
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| Institution: | Institute for Chemical Research, Kyoto University, Uji, Kyoto 611, Japan |
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| Abstract: | Treatment of several cyclic olefins, β-pinene, allylbenzene, and estragole with palladium(II) salt in acetic acid in the presence of t-butyl hydroperoxide and tellurium(IV) oxide afforded mainly the corresponding allylic acetates. The reaction proceeded catalytically with palladium(II) salt, t-BuOOH working as a reoxidizing agent. |
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