The simplest binary fluorocarbon as a ligand. Synthetic, spectroscopic, crystallographic, and computational studies of a molybdenum complex of terminally ligated carbon monofluoride (fluoromethylidyne) |
| |
Authors: | Huang Hui Hughes Russell P Landis Clark R Rheingold Arnold L |
| |
Affiliation: | Department of Chemistry, Dartmouth College, Hanover, New Hampshire 03755, USA. |
| |
Abstract: | Cp*Mo(CO)3CF3 undergoes two-electron reduction using potassium graphite or magnesium graphite to give Cp*Mo(CO)2(CF), the first example of a transition metal complex containing a terminal fluoromethylidyne ligand, which has been characterized spectroscopically, crystallographically, and computationally. |
| |
Keywords: | |
本文献已被 PubMed 等数据库收录! |
|