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Selective synthesis of mono-alkyldichlorosilanes via the reaction of olefins with dichlorosilane catalyzed by group VIII metal phosphine complexes |
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| Authors: | Hamao Watanabe Masafumi Aoki Noritaka Sakurai Ken-ichi Watanabe Yoichiro Nagai |
| Abstract: | In the hydrosilylation of 1-hexene with dichlorosilane, many phosphine complexes of group VIII metals, Ni, Ru, Rh, PD and Pt, were found to be active catalysts, giving n-hexyldichlorosilane exclusively. Tris(triphenylphosphine)chlororhodium was found to be the most convenient and effective catalyst for the selective synthesis of mono-organodichlorosilanes. |
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