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Growth and properties of monocrystals for miniature lasers
Affiliation:1. Beijing Key Laboratory of Environmental Science and Engineering, School of Chemical Engineering and the Environment, Beijing Institute of Technology, Beijing 100081, China;2. Ningde Amperex Technology Ltd, Research Institute, Ningde 352100, China;3. National & Local United Engineering Laboratory for Power Battery, Institute of Functional Materials, Department of Chemistry, Northeast Normal University, Changchun 130024, China;4. Hongsen Material Co,. Ltd., Guangzhou 510730, China;1. Laboratory of Oxide Systems, Baikal Institute of Nature Management, SB RAS, Ulan-Ude 670047, Russia;2. Department of Chemistry, Buryat State University, Ulan-Ude 670000, Russia;3. Laboratory of Optical Materials and Structures, Rzhanov Institute of Semiconductor Physics, SB RAS, Novosibirsk 630090, Russia;4. Functional Electronics Laboratory, Tomsk State University, Tomsk 634050, Russia;5. Laboratory of Semiconductor and Dielectric Materials, Novosibirsk State University, Novosibirsk 630090, Russia;6. Laboratory of Crystal Chemistry, Nikolaev Institute of Inorganic Chemistry, SB RAS, Novosibirsk 630090, Russia;7. Department of Natural Sciences, Novosibirsk State University, Novosibirsk 630090, Russia;8. Laboratory of Molecular Spectroscopy, Kirensky Institute of Physics, SB RAS, Krasnoyarsk 660036, Russia;9. Laboratory of Epitaxial Layers, Nikolaev Institute of Inorganic Chemistry, SB RAS, Novosibirsk 630090, Russia;10. Laboratory of Research Methods of Composition and Structure of Functional Materials, Novosibirsk State University, Novosibirsk 630090, Russia;11. Laboratory of Crystal Structure, Kirensky Institute of Physics, SB RAS, Krasnoyarsk 660036, Russia;12. Department of Photonics and Laser Technology, Siberian Federal University, Krasnoyarsk 660079, Russia;13. Laboratory of Condenced Matter Spectroscopy, Institute of Automation and Electrometry, SB RAS, Novosibirsk 90, 630090, Russia;1. College of Chemistry, Jilin University, Changchun 130026, PR China;2. Department of Chemistry, Tonghua Normal University, Tonghua 134002, PR China;1. Science College, Hunan Agricultural University, Changsha 410128, China;2. School of Chemical Engineering, North China University of Science and Technology, Tangshan 063009, China;1. Laboratoire d''Etude sur les Interactions Matériaux-Environnement (LIME), Université Mohamed Seddik Ben Yahia, BP 98 Ouled Aissa, 18000 Jijel, Algeria;2. Département de Chimie, Faculté des Sciences Exactes et Informatique, Université Mohamed Seddik Ben Yahia, BP 98 Ouled Aissa, 18000 Jijel, Algeria;3. Institut de Recherche de Chimie Paris, IRCP, UMR 8247 du CNRS, ChimieParisTech (PSL), ENSCP 11 rue Pierre et Marie Curie 75231, Paris Cedex 05, France;4. University of Namur, Research Center on Physics of Matter and Radiation (PMR), 61, rue de Bruxelles, 5000 Namur, Belgium
Abstract:We have considered the special features of growth for the Nd compounds in the form of monocrystals containing a high concentration of Nd ions (>1021 ions/cm3) with an anamolously low concentration quenching. These compounds are known popularly as “nezoites” containing isolated Nd polyhedra in the structure, which gives a clue to the technology of growth. All the known nezoite crystals, their X-ray analyses and the conditions of growth from multicomponent systems are tested. At present there are two well-known methods of growing nezoites: (1) by evaporation of the solvent at constant temperature and pressure; and (2) by flux method. The authors have discussed the advantages and disadvantages of these two methods. The problem of the presence of light extinguishing admixtures, particularly (OH) molecules in the crystals, and the influence of these admixtures on the basic properties of these crystals (nezoites) is discussed in detail.
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