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Noroleanane Triterpenoids from the Aerial Parts of Lantana camara
Authors:Sabira Begum  Syeda Qamar Zehra  Syed Imran Hassan  Bina S Siddiqui
Institution:H.E.J. Research Institute of Chemistry, International Center for Chemical and Biological Sciences, University of Karachi, Karachi‐75270 Pakistan
Abstract:Two novel triterpenoids, lantadienone ( 1 ) and camaradienone ( 2 ), were isolated from the aerial parts of Lantana camara, along with seven known compounds, lantadene A, lantadene B, β‐sitosterol 3‐(β‐D ‐glucopyranoside), camaric acid, lantanilic acid, lantanolic acid, and camangeloyl acid. Their structures were elucidated as (3β,22β)‐3,25‐epoxy‐3‐hydroxy‐22{(2Z)‐2‐methyl‐1‐oxobut‐2‐enyl]oxy}‐28‐noroleana‐12,17‐dien‐11‐one ( 1 ) and (3β)‐3,25‐epoxy‐3‐hydroxy‐28‐noroleana‐12,17‐dien‐11‐one ( 2 ), respectively, by means of spectral studies. The triterpenoids 1 and 2 represent 28‐noroleananes oxidized at C(11) and C(22) or at C(11), reported for the first time.
Keywords:Lantana camara  Lantadienone  Camaradienone  Triterpenoids  Noroleananes
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