Intrachain versus Interchain Electron Transport in Poly(fluorene‐alt‐benzothiadiazole): A Quantum‐Chemical Insight |
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| Authors: | Antoine Van Vooren Ji‐Seon Kim Prof Jérôme Cornil Dr |
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| Institution: | 1. Laboratory for Chemisty of Novel Materials, University of Mons‐Hainaut, Place du Parc 20, 7000 Mons, Belgium, Fax: : (+32)?65‐373861;2. Blackett Laboratory, Imperial College London, Prince Consort Road, London SW7?2BW, UK |
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| Abstract: | Poly(9,9‐di‐n‐octylfluorene‐alt‐benzothiadiazole) F8BT], displays very different charge‐transport properties for holes versus electrons when comparing annealed and pristine thin films and transport parallel (intrachain) and perpendicular (interchain) to the polymer axes. The present theoretical contribution focuses on the electron‐transport properties of F8BT chains and compares the efficiency of intrachain versus interchain transport in the hopping regime. The theoretical results rationalize significantly lowered electron mobility in annealed F8BT thin films and the smaller mobility anisotropy (μ∥/μ⊥) measured for electrons in aligned films (i.e. 5–7 compared to 10–15 for holes). |
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| Keywords: | electron transfer electron transport polymers quantum chemistry thin films |
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