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N,N,N′,N′‐Tetrabromobenzene‐1,3‐Disulfonamide and Poly(N‐Bromo‐N‐Ethyl‐Benzene‐1,3‐Disulfonamide) as Efficient Catalysts for the Methoxymethylation of Alcohols under Solvent‐Free Conditions
Authors:Ramin Ghorbani‐Vaghei  Mohammad Ali Zolfigol  Mostafa Amiri  Hojat Veisi
Institution:Department of Organic Chemistry, Faculty of Chemistry, Bu‐Ali Sina University, Hamadan, 65174, Iran
Abstract:Methoxymethylation of a variety of alcohols was performed using formaldehyde dimethyl acetal in the presence of N,N,N′,N′‐tetrabromobenzene‐1,3‐disulfonamide TBBDA] and poly(N‐bromo‐N‐ethylbenzene‐1,3‐disulfonamide) PBBS] as catalysts at room temperature and solvent‐free conditions. The methoxymethyl ethers (MOM‐ethers) were obtained with good to excellent yields.
Keywords:Alcohols  Formaldehyde dimethyl acetal  TBBDA  PBBS  Solvent‐free conditions
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