N,N,N′,N′‐Tetrabromobenzene‐1,3‐Disulfonamide and Poly(N‐Bromo‐N‐Ethyl‐Benzene‐1,3‐Disulfonamide) as Efficient Catalysts for the Methoxymethylation of Alcohols under Solvent‐Free Conditions |
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Authors: | Ramin Ghorbani‐Vaghei Mohammad Ali Zolfigol Mostafa Amiri Hojat Veisi |
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Institution: | Department of Organic Chemistry, Faculty of Chemistry, Bu‐Ali Sina University, Hamadan, 65174, Iran |
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Abstract: | Methoxymethylation of a variety of alcohols was performed using formaldehyde dimethyl acetal in the presence of N,N,N′,N′‐tetrabromobenzene‐1,3‐disulfonamide TBBDA] and poly(N‐bromo‐N‐ethylbenzene‐1,3‐disulfonamide) PBBS] as catalysts at room temperature and solvent‐free conditions. The methoxymethyl ethers (MOM‐ethers) were obtained with good to excellent yields. |
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Keywords: | Alcohols Formaldehyde dimethyl acetal TBBDA PBBS Solvent‐free conditions |
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