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Enantioselective 1,3‐dipolar cycloaddition reactions using complexes of (−)‐sparteine
Authors:Mirosław Gucma  W Marek Gołȩbiewski
Institution:Institute of Industrial Organic Chemistry, 03–236 Warsaw, Poland
Abstract: chemical structure image Regio‐ and stereoselective 1,3‐dipolar cycloaddition of nitrile oxides to internal 2‐pentenols and α,β‐unsaturated esters catalyzed by (?) sparteine‐lanthanide complexes affords corresponding 3‐aryl‐2‐isoxazolines with enantioselectivities up to 68% ee.
Keywords:
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