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Gas‐phase thermolysis of benzotriazole derivatives. Part 4. Pyrolysis of 1‐acylbenzotriazole phenylhydrazones. Interesting direct routes towards N‐aminobenzimidazoles
Authors:Hanan Al‐Awadi  Maher R Ibrahim  Nouria A Al‐Awadi  Yehia A Ibrahim
Institution:Chemistry Department, Faculty of Science, Kuwait University, P.O. Box 5969, Safat 13060, Kuwait
Abstract: chemical structure image Flash vacuum pyrolysis (FVP) of 1‐acylbenzotriazole phenylhydrazones gave benzonitriles, aniline and 2‐arylbenzimidazole derivatives. Static pyrolysis of the same substrates at 180 °C gave exclusively the corresponding N‐anilino‐2‐arylbenzimidazole derivatives. Pyrolysis of the isomeric 2‐acylbenzotriazole phenylhydrazones gave similar products.
Keywords:
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