Nanoelectrocatalyst Based on High‐Density Au/Pt Hybrid Nanoparticles Supported on a Silica Nanosphere |
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Authors: | Shaojun Guo Junfeng Zhai Youxing Fang Shaojun Dong Prof. Erkang Wang Prof. |
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Affiliation: | 1. State Key Laboratory of Electroanalytical Chemistry, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, Jilin (China);2. Graduate School of the Chinese Academy of Sciences, Beijing, 100039 (China), Fax: (+86)431‐8568‐9711 |
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Abstract: | A high‐efficiency nanoelectrocatalyst based on high‐density Au/Pt hybrid nanoparticles supported on a silica nanosphere (Au‐Pt/SiO2) has been prepared by a facile wet chemical method. Scanning electron microscopy, transmission electron microscopy, energy‐dispersive X‐ray spectroscopy, and X‐ray photoelectron spectroscopy are employed to characterize the obtained Au‐Pt/SiO2. It was found that each hybrid nanosphere is composed of high‐density small Au/Pt hybrid nanoparticles with rough surfaces. These small Au/Pt hybrid nanoparticles interconnect and form a porous nanostructure, which provides highly accessible activity sites, as required for high electrocatalytic activity. We suggest that the particular morphology of the Au‐Pt/SiO2 may be the reason for the high catalytic activity. Thus, this hybrid nanomaterial may find a potential application in fuel cells. |
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Keywords: | electrochemistry fuel cell gold nanostructures X‐ray absorption spectroscopy |
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