Supramolecular Assembly of β‐Cyclodextrin‐Capped Gold Nanoparticles on Ferrocene‐Functionalized ITO Surface for Enhanced Voltammetric Analysis of Ascorbic Acid |
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| Authors: | Fang Zuo Chunhua Luo Zhaohui Zheng Xiaobin Ding Yuxing Peng |
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| Affiliation: | 1. Chengdu Institute of Organic Chemistry, Chinese Academy of Sciences, Chengdu 610041, P.?R. China;2. Graduate School of the Chinese Academy of Sciences, Beijing 100081, P.?R. China |
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| Abstract: | A supramolecular recognition functionalized electrode (βCD‐nanoAu/Fc‐ITO) which exhibits redox‐activity was prepared through supramolecular assembly of β‐cyclodextrin (βCD) capped gold nanoparticles (βCD‐nanoAu) on the ITO previously coated with a monolayer of ferrocene residues (Fc‐ITO). The immobilization of βCD‐nanoAu on Fc‐ITO was confirmed by atomic force microscopy (AFM), and the supramolecular nature of the immobilization approach was also confirmed by cyclic voltammetry. On the other hand, the electrocatalytic activity of βCD‐nanoAu/Fc‐ITO electrode was also studied. The electrocatalytic activity toward ascorbic acid (AA) was enhanced compared with that at the Fc‐ITO electrode, and a linear relationship existed between the anodic peak and the concentration of AA in the range of 5.3×10?5 to 3.0×10?3 M with a detection limit (S/N=3) of 4.1×10?6 M. |
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| Keywords: | β ‐Cyclodextrin Gold nanoparticles Supramolecular Assembly Ascorbic acid |
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