Enhanced Removal of Cu(II) and Pb(II) from Aqueous Solutions by Pretreated Biomass of Fusarium Solani |
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Authors: | Haq Nawaz Bhatti Ghufrana Samin Muhammad Asif Hanif |
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Affiliation: | 1. Industrial Biotechnology Laboratory, Department of Chemistry and Biochemistry, University of Agriculture, Faisalabad‐380400, Pakistan;2. Rose Laboratory, Institute of Horticultural Sciences, University of Agriculture, Faisalabad‐380400, Pakistan |
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Abstract: | This study investigated the feasibility of Fusarium solani biomass as a biosorbent for Cu(II) and Pb(II) removal from aqueous solutions. Batch sorption experiments were carried out for Cu(II) and Pb(II) to quantify the sorption kinetics, pH, biosorbent dose and pretreatment of F. solani biomass. Biomass metal uptake clearly competed with protons present in the aqueous medium, making pH an important variable in the process. The maximum biosorption by F. solani biomass was obtained with solutions having pH 5 for both metal ions. An enhanced Cu(II) removal (96.53%) was observed for aluminum hydroxide pretreated biomass. Maximum Pb(II) removal (95.48%) was observed with native biomass. Time dependence experiments for the metal ions uptake showed that adsorption equilibrium reached almost 240 min after metal addition. The kinetic studies showed that the biosorption process followed the pseudo second‐order rate model for Cu(II) and Pb(II). The equilibrium data fitted well to the Langmiur isotherm model. |
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Keywords: | Fusarium solani Pretreatments Biosorption Cu(II) Pb(II) Kinetics |
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