Preparation and thermal decomposition reaction kinetics of a dysprosium(III) p‐chlorobenzoate 1,10‐phenanthroline complex |
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| Authors: | Jian Jun Zhang Su Ling Xu Ning Ren Hai Yan Zhang Liang Tian |
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| Institution: | 1. Experimental Center, Hebei Normal University, Shijiazhuang 050016, People's Republic of China;2. College of Chemistry & Material Science, Hebei Normal University, Shijiazhuang 050016, People's Republic of China;3. Department of Chemistry, Handan College, Handan 056005 People's Republic of China |
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| Abstract: | The title complex Dy(p‐ClBA)3Phen]2·2H2O was synthesized, where p‐ClBA is p‐chlorobenzoate and Phen is 1,10‐phenanthroline. The complex was characterized by various techniques including elemental analysis, IR, XRD, and molar conductance. The thermal decomposition of the complex was studied under the nonisothermal condition by TG‐DTG and IR techniques. The kinetic parameters of dehydration process were obtained from the analysis of DSC curves of the complex by the NL‐DIF and Popescu methods, respectively. © 2007 Wiley Periodicals, Inc. 40: 66–72, 2008 |
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