Novel Electrochemical Microsensor for Hydrogen Peroxide based on Iron‐Ruthenium Hexacyanoferrate Modified Carbon Fiber Electrode |
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Authors: | Rasa Pauliukaite Samo B Hočevar Emily A Hutton Božidar Ogorevc |
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Institution: | 1. Institute of Chemistry, Vilnius, Lithuania;2. Analytical Chemistry Laboratory, National Institute of Chemistry, P.?O. Box 660, SI‐1001 Ljubljana, Slovenia |
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Abstract: | Novel electrochemical microsensor based on mixed iron‐ruthenium hexacyanoferrate (FeRuHCF) modified carbon fiber microelectrode (CFME) is presented for voltammetric and amperometric measurement of hydrogen peroxide at physiological pH. The FeRuHCF coating was electrochemically deposited using a one step procedure onto the substrate carbon fiber microelectrode by cycling the potential between 0.0 and +1.0 V (vs. Ag/AgCl) in a solution containing all precursor salts. The microsensor displayed good stability in neutral and alkaline media and had a nonstop working lifetime of up to 12 hours. The amperometric response time varied from 5 to 15 s depending on the hydrogen peroxide concentration level. The newly developed electrochemical microsensor exhibited a highly linear behavior in the examined concentration range from 5 to 1000 μmol L?1 (R2=0.999), an LoD (3σ) of 0.9 μmol L?1, and a favorable reproducibility with a calculated RSD of 2.9% (n= 6) for 100 μmol L?1 hydrogen peroxide, thus holding great promise for its further application in real samples and its exploitation in combination with biorecognition elements in advanced microbiosensor design. |
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Keywords: | Hydrogen peroxide Mixed‐metal hexacyanoferrate Microelectrode Modified electrode Amperometry Iron Ruthenium |
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