One and Two-dimensional Structures of a New Oxamido Copper(II) Complex with Phthalato Bridged |
| |
作者姓名: | 陈静 姜宗慧 廖代正 闫世平 |
| |
作者单位: | Department of Chemistry,Nankai University,Tianjing 300071,China,Department of Chemistry,Nankai University,Tianjing 300071,China State Key Laboratory of Coordination Chemistry,Nanjing 210093,China,Department of Chemistry,Nankai University,Tianjing 300071,China,Department of Chemistry,Nankai University,Tianjing 300071,China |
| |
基金项目: | This project was supported by the National Natural Science Foundation of China (No 20331010) and Natural Science Foundation of Tianjing (No. 033602011) |
| |
摘 要: | 1 INTRODUCTION Coordination polymers are a family of materials composed of 1D chains, 2D sheets, and 3D networks of metal-organic building blocks connected via co- valent and hydrogen bonds. Recently, they have re- ceived increasing attention for their fascinating struc- tures and topological features1~4]. The complex as ligands approach is one of the best strategies to de- sign and synthesize polynuclear species, and a good example of ‘complex ligand’ is represented by mono- nuclear…
|
One and Two-dimensional Structures of a New Oxamido Copper(II) Complex with Phthalato Bridged |
| |
Abstract: | A new o-phthalato-bridged oxamide copper(II) complex 1, {Cu2(oxap)](pht)(4H2O}n (oxap = N, N′-bis(2-aminopropyl)oxamide, pht = phthalate dianion), has been prepared and structurally characterized. It crystallizes in monoclinic, space group C2/c with a = 23.424(4), b = 7.9696(14), c = 15.727(3) , β = 129.617(2)o, C16H28Cu2N4O10, Mr = 563.50, V = 2261.6(7) 3, Z = 4, Dc = 1.655 g/cm3, μ(MoKα) = 1.939 mm-1, F(000) = 1160, the final R = 0.0393 and wR = 0.0928 for 1707 observed reflections with I > 2((I). Single-crystal X-ray analysis reveals that 1 displays a one-dimensional zigzag chain structure, in which each Cu(oxap) moiety adopting trans-confor- mation is connected by μ1,6-phthalate anion bridges, and these zigzag chains are further linked by another μ1,6-phthalate anion bridge to form a 2D sheet structure. The polar guest water molecules reside in the inter- and intrasheets to stabilize the whole crystal structure. |
| |
Keywords: | phthalate oxamide bridged copper(II) complex crystal structure host-guest |
本文献已被 CNKI 等数据库收录! |
|