| Preparation of Ionic Liquids and Their Application in Hydrogenation of Aromatic Nitriles |
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| 引用本文： | LIN,Qi CHEN,Li XIE,Yi-Peng ZHENG,Hong-Jie LI,Xian-Jun CHEN,Hua. Preparation of Ionic Liquids and Their Application in Hydrogenation of Aromatic Nitriles[J]. 有机化学, 2004, 24(Z1): 252 |
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| 作者姓名： | LIN Qi CHEN Li XIE Yi-Peng ZHENG Hong-Jie LI Xian-Jun CHEN Hua |
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| 作者单位： | LIN,Qi（Key Labortory of Green Chemistry and Technology, Ministry of Education, Institute of Homogeneous Catalysis, College of Chemistry, Sichuan University, Chengdu 610064;Department of Chemistry, Minjiang University, Fuzhou 350011） CHEN,Li（Key Labortory of Green Chemistry and Technology, Ministry of Education, Institute of Homogeneous Catalysis, College of Chemistry, Sichuan University, Chengdu 610064） XIE,Yi-Peng（Key Labortory of Green Chemistry and Technology, Ministry of Education, Institute of Homogeneous Catalysis, College of Chemistry, Sichuan University, Chengdu 610064） ZHENG,Hong-Jie（Key Labortory of Green Chemistry and Technology, Ministry of Education, Institute of Homogeneous Catalysis, College of Chemistry, Sichuan University, Chengdu 610064） LI,Xian-Jun（Key Labortory of Green Chemistry and Technology, Ministry of Education, Institute of Homogeneous Catalysis, College of Chemistry, Sichuan University, Chengdu 610064） CHEN,Hua（Key Labortory of Green Chemistry and Technology, Ministry of Education, Institute of Homogeneous Catalysis, College of Chemistry, Sichuan University, Chengdu 610064） |
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| 摘 要： | On the basis of their characteristic polar nature, phase behavior and lack of vapour pressure, ionic liquids are considered as green solvents and have attracted significant attention as an alternative reaction medium for homogeneous catalysis.[1] However, the "greenness" of typical ionic liquids used in the literature consisted of halogen-containing anions (such as [AlCl4]-, [BF4]- and [PF6]-) was limited in some sense, due to the serious environment concerns if the hydrolysis stability of the anion is poor (e.g. for [AlCl4]-and [PF6]-) or thermal stability of used ionic liquid is undesired. In both cases, the additional effort is needed to avoid the liberation of toxic and corrosive HF or HCl into the environment.
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Preparation of Ionic Liquids and Their Application in Hydrogenation of Aromatic Nitriles |
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| LIN Qi,CHEN Li,XIE,Yi-Peng,ZHENG,Hong-Jie,LI,Xian-Jun,CHEN,Hua. Preparation of Ionic Liquids and Their Application in Hydrogenation of Aromatic Nitriles[J]. Chinese Journal of Organic Chemistry, 2004, 24(Z1): 252 |
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| Authors: | LIN Qi CHEN Li XIE Yi-Peng ZHENG Hong-Jie LI Xian-Jun CHEN Hua |
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| Abstract: | On the basis of their characteristic polar nature, phase behavior and lack of vapour pressure, ionic liquids are considered as green solvents and have attracted significant attention as an alternative reaction medium for homogeneous catalysis.[1] However, the "greenness" of typical ionic liquids used in the literature consisted of halogen-containing anions (such as [AlCl4]-, [BF4]- and [PF6]-) was limited in some sense, due to the serious environment concerns if the hydrolysis stability of the anion is poor (e.g. for [AlCl4]-and [PF6]-) or thermal stability of used ionic liquid is undesired. In both cases, the additional effort is needed to avoid the liberation of toxic and corrosive HF or HCl into the environment. |
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