| 基于原油中金刚烷指纹半定量分析进行原油鉴别 |
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| 引用本文： | 张魁英,杨佰娟,郑立,臧家业,詹天荣,王小如,黎先春. 基于原油中金刚烷指纹半定量分析进行原油鉴别[J]. 分析化学, 2011, 39(4): 496-500. DOI: 10.3724/SP.J.1096.2011.00496 |
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| 作者姓名： | 张魁英 杨佰娟 郑立 臧家业 詹天荣 王小如 黎先春 |
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| 作者单位： | 国家海洋局第一海洋研究所海洋生态研究中心;青岛科技大学化学与分子工程学院; |
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| 基金项目： | 海洋公益性行业科研专项项目(No.200705011); 海洋环境保护及节能减排专项项目; 国家海洋局青年海洋科学基金(No.2010518); 国家自然科学基金(Nos.41076108,40806053,20905017); 国家海洋局海洋溢油鉴别与损害评估技术重点实验室开放基金(No.201013); 生态环境科学与工程重点实验室开放基金(No.MESE-2010-08)项目资助 |
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| 摘 要： | 采用气相色谱质谱联用(GC-MS)技术,建立了原油中金刚烷化合物内标法半定量的分析方法,确定了基于谱图特征和计算保留指数的组分定性方法,对26种单金刚烷、双金刚烷化合物进行了定性与定量分析.对不同地理位置海上油井平台6个原油金刚烷指纹进行了分析.研究表明,原油中单金刚烷总含量在200～1200 μg/g之间,双金刚烷总...
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| 关 键 词： | 原油 金刚烷指纹 半定量法 气相色谱-质谱 |
Crude Oil Identification Based on Diamondoid Fingerprinting Concentrations by Semiquantitative Method |
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| ZHANG Kui-Ying,YANG Bai-Juan,ZHENG Li,ZANG Jia-Ye,ZHAN Tian-Rong,WANG Xiao-Ru,Frank S. C. Lee. Crude Oil Identification Based on Diamondoid Fingerprinting Concentrations by Semiquantitative Method[J]. Chinese Journal of Analytical Chemistry, 2011, 39(4): 496-500. DOI: 10.3724/SP.J.1096.2011.00496 |
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| Authors: | ZHANG Kui-Ying YANG Bai-Juan ZHENG Li ZANG Jia-Ye ZHAN Tian-Rong WANG Xiao-Ru Frank S. C. Lee |
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| Affiliation: | ZHANG Kui-Ying1,2,YANG Bai-Juan1,ZHENG Li1,ZANG Jia-Ye1,ZHAN Tian-Rong2,WANG Xiao-Ru1,Frank S.C.Lee1 1(Research Center for Marine Ecology,The First Institute of Oceanography,State Oceanic Administration,Qingdao 266061)2(College of Chemistry and Molecular Ensineering,Qingdao University of Science and Technology,Qingdao 266042) |
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| Abstract: | A semiquantitative gas chromatography-mass spectrometry(GC-MS) with internal standard method was developed for the fingerprinting analysis of diamondoid compounds in crude oils.Based on the chromatograms properties and the calculated retention indices,26 diamondoid compounds were analyzed qualitatively and the concentration formula of semiquantitative using the internal standard(d16-adamandane) were provided.Diamondoids fingerprinting of 6 crude oils from different offshore oil platform were analyzed.The re... |
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| Keywords: | Crude oil Diamondoid fingerprinting Semiquantitative method |
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